After the story you unlock Chapter Select and keep all of your equipment. Play the Combat Simulator Mission against Malboro, which is exclusive to HARD difficulty. Monsters of Legend” – only available on HARD difficulty via Chapter Select – not obtainable on Normal / Easy / Classic).
Enemy Skill #4: Bad Breath – Learned from Malboro (Chapter 17 – Combat Simulator Mission “Three-Person Team vs. Shortly after the start of Chapter 15 you will run into a group of Cerulean Drakes. Enemy Skill #3: Algid Aura – Learned from Cerulean Drake (Chapter 15 / Objective: The Climb / Area: 55M Above Ground Level – Distillation Tower 2, 3F). 
Defeat it and it will always self-destruct after a few seconds. A Smogger is found walking north-east of the Sector 5 Slums town in the Steel Mountain map section.
Enemy Skill #2: Self-Destruct – Learned from Smogger (Chapter 14 / Objective: Intel Gathering / Area: Sector 5 Slums Area – Steel Mountain). Enemy Skill #1: Spirit Siphon – Learned from Phantom / Varghidpolis / Bomb (Chapter 14 – Missing Children Side Quest – You encounter Phantom enemy at the end of the quest, the screenshot below shows the quest’s starting point). None of the Final Fantasy 7 Remake Enemy Skills are missable because you unlock Chapter Select after the story and can go back everywhere. You also get a green flash on the screen that says “Learned”. Then the enemy just needs to hit you once with their skill and you will unlock it permanently under your abilities in the Command Menu (that’s how you can keep track which ones you got). It is important you have the Enemy Skill Materia equipped or else it won’t work! Make sure you are actively controlling the character who has it equipped.
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